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　安田　源

やすだ　はじめ (YASUDA, Hajime)

理学修士（大阪大学)(1965) , 理学博士（大阪大学）(1970)

生年： 1941年生

学歴：

大阪大学理学部高分子学科卒業(1963)，大阪大学大学院理学研究科高分子学専攻修士課程専攻修了(1965),　大阪大学大学院理学研究科高分子学専攻博士課程後期中退(1966)

職歴：

大阪大学理学部助手(1966), 大阪大学理学部助教授(1983)，広島大学工学部教授(1992)

2004年3月　定年退官

広島大学名誉教授

専門分野：　　有機金属化学、高分子化学

研究内容：

[1]遷移金属錯体による極性および非極性モノマーのリビング重合、[2]微粒子金属が分散した炭素材の合成と吸着作用、[３]生分解性ポリマーの開発

主要論文：

[1] H. Tamai, T. Kakii, T. Kumamoto, and H. Yasuda, Synthesis of Extremely Large Masoporous Activated Carbon and Its Unique Adsorption for Giant Molecules, Chem. Mater. 8, 454 (1996).

[2] H. Tamai, M. Ikeuchi, S. Kojima, and H. Yasuda, Extremely Large Mesoporous Carbon Fibers Synthesized by the Addition of Rare Earth Metal Complexes and Their Unique Adsorption Behavior, Adv. Mater., 9, 55 (1997).

[3] H. Tamai, H. Yasuda, T. Tanaka, J. Mondori, K. Nadai, and K. Kaneko,Pore Structure of Acivated Carbon Fibers from Organometallic/Pitch Composites by Nitrogen Adsorption, M. E-Merrauui, Carbon, 36, 1769-1776 (1998).

[4] H. Tamai, T. Ikeya, F. Nishiyama, H. Yasuda, K. Iida, and S. Nojima, NO Decomposition by Noble Metals Surrounding the Rare Earth Phosphate Hollow Patrticles, J. Mater. Sci. 35,4945 (2000).

[5] H. Tamai, T. Ikeya, and H. Yasuda, Hydrogenation of 1-Hexene and Hexadienes by Pd Metal Attached to the Surface of PrPO4 Hollow Particles, J. Colloid Interf. Sci., 218, 217 (1999).

[6] H. Tamai, T. Yoshida, M. Sasaki, and H. Yasuda, Dye Adsorption on Mesoporous Activated Carbon Fiber Obtained from Pitch Containing Yttrium Complex, Carbon, 37, 983 (1999).

[7] H. Tamai, and H. Yasuda, Preparation of Polymer Particles Coated with Hydroxyapatite, J. Colloid. Interf. Sci., 212, 585 (1999).

[8] H. Tamai, Y. Kataoka, F. Nishiyama, and H. Yasuda, Characteristics and Catalytic Activity of Carbons Obtained From Pitch Containing Noble Metal Complexes, Carbon, 38, 899 (2000).

[9] H. Tamai, H. Sugahara, and H. Yasuda, Preparation of Carbons From Pitch Containing Polysilane and Their Anode Properties for Lithium-ion Batteries, J. Mater. Sci. Let., 19, 53 (2000).

[10] M. Morita, S. Watanabe, M. Ishikawa, H. Tamai, and H. Yasuda,Utilization of Activated Carbon Fiber with Mesopore Structure for Electric Double Layer Capacitors, Electrochemistry, 69, 462 (2001).

[11] H. Tamai, S. Matsuoka, M. Ishihara, and H. Yasuda, New Carbon Materials from Pitch Containing Organotin Compounds for Anode of Lithium Ion Batteries, Carbon, 39, 1515 (2001).

[12] H. Yasuda, E. Ihara, Y. Nitto, T. Kakehi, M. Morimoto, and M. Nodono,Organo Rare Earth Metal Initiated Living Polymerizations of Polar and Nonpolar Monomers, A. O. Patil, D. N. Schulz, B. M. Novak, edts. ACS Symposium Series 704, 149 (1998).

[13] E. Ihara, Y. Adachi, H. Hashimoto, N. Kanehisa, and Y. Kai, Synthesis of 2,6-Dialkoxyphenyllanthanoid Complexes and Their Polymerization Catalysis, J. Organomet. Chem., 569, 147 (1998).

[14] E. Ihara, M. Nodono, K. Katsura, Y. Adachi, H. Yasuda, M. Yamagashira, H. Hashimoto, N. Kanehisa, and Y. Kai, Synthesis and Olefin Polymerization Catalysis of New Divalent Samarium Complexes with Bridging Bis(cyclopentadienyl) Ligands, Organometallics 17, 3945 (1998).

[15] E. Ihara, K. Koyama, H. Yasuda, N. Kanahisa, and Y. Kai, Catalytic Activity of Allyl-, Azaallyl- and Diaza-pentadienyllanthanide Complexes for Polymerization of Methyl Methacrylate, J. Organomet. Chem.. 574, 40 (1999).

[16] H. Yasuda, M. S. Aludin, N. Kitamura, M. Tanabe, and H. Shirahama, Synthesis and Physical Properties of Novel Optically Active Poly(ester-carbonate)s by Copolymerization of Substituted Trimethylene Carbonate with Caprolactone and Their Biodegradation Behavior, Macromnolecules, 32, 6047 (1999).

[17] H. Yasuda, Organo Transition Metal Initiated Living Polymerization, Prog. Polym. Sci., 25, 573 (2000).

[18] H. Yasuda, Living or Radical? J. Polym. Sci. Polym. Chem., 38, 1752 (2000).

[19] E. Ihara T. Fujimura, H. Yasuda, T. Maruo, N. Kanehisa, and Y. Kai, High Polymerization of Methyl Methacrylate with Organonickel/MMAO Systems, J. Polym. Sci. Polym. Chem. Ed., 38, 4764 (2000).

[20] K. Tanaka, M. Furo, E. Ihara, H. Yasuda, Unique Dual Functions of La(C5Me5)[CH(SiMe3)2]2(THF) for Non-polar and Polar Monomers, J. Polym. Sci. Polym. Chem. Ed. 39, 1382 (2001).

[21] E. Ihara, Y. Maeno, and H. Yasuda, Polymerization of Methyl Methacrylate with Homogeneous Organo- palladium/ MMAO Systems, Macromol. Chem. Phys., 202, 1518 (2001).

[22] E. Ihara, M. Tanaka, H. Yasuda, N. Kanehisa, T. Maruo, and Y. Kai, Coordination of Allenyl/Propagyl Group to Samarium(III): The First Crystal Structures of h3-Allenyl and h1-Propagyl Lanthanide Complexes, J. Organomet. Chem., 613, 26 (2000).

[23] H. Nakamura, H. Yasuda, T. Maruo, N. Kanehisa, Y. Kai, Reversible h5-h6 Rearrangement of Bis(fluorenyl)lanthanide Complexes by Reactions with AlR3, Organometallics, 19, 5392 (2000).

[24] Desurmont, M. Tanaka, Y. Li, and H. Yasuda. New Approach to Block Copolymerization of Ethylene with Polar Monomers by the Unique Catalytic Function of Organolanthanide Complexes, G. J. Polym. Sci. Polym. Chem. Ed., 38, 4095-4109 (2000).

[25] E. Ihara, S. Yoshioka, M. Furo, K. Katsura, H. Yasuda, S. Mohri, N. Kanehisa, and Y. Kai, Synthesis and Olefin Polymerization Catalysis of New Trivalent Samarium and Yttrium Complexes with Bridging Bis(cycloprentadienyl) Ligands, Organometallics, 20, 1752 (2001).

[26] G. Desurmont and H. Yasuda, First Controlled Block Coplymrerization of Higher 1-Olefins with Polar Monomers Using Metallocene Type Single Component Lanthanide, Macromolecules, 33, 7679 (2000).

[27] G. Desurmont, Y. Li, H. Yasuda, T. Maruo, N. Kanehisa, Y. Kai, Reaction Pathway for the Formation of Binuclear Samarocene Hydride from Monomeric Alkyl Samarocene Derivative, Organometallics, 19, 1811 (2000).

[28] H. Yasuda, E. Ihara, T. Fujimura, Y. Maeno, K. Ogata, Y. Sato, and G. Desurmont,New Approachs in Polymerizations Using Transition Metal Complexes, Synth. Org. Chem., 58, 1084 (2000).

[29] H. Yasuda, Rare Earth Metal Initiated Polymerizations of (Mth)acrylates and Block Copolymerizations of Olefins with Polar Monomers, J. Polym. Sci. Polym. Chem., 39, 1955 (2001).

[30] T. Mizumoto, N. Sugimura, M. Moritani, H. Yasuda, Y. Sato, and H. Masuoka, Supercritical CO2-Induced Stereocomplex Formation of Highly Stereoregular Isotactic Poly(methyl methacrylate) and Syndiotactic Poly(methyl methacrylate) Blends: Effect of Molecular Weight on Crystalline Structure, Macromolecules, 34, 5200 (2001).

[31] H. Shirahama, M. Shiomi, M. Sakane, and H. Yasuda, Biodegradation of Novel Optically Active Polyesters Synthesized by Copolymerization of (R)-MOHEL with Lactones, Macromolecules, 29, 4821 (1996).

[32] H. Shirahama, K. Umemoto, and H. Yasuda, Synthesis and Enzyme Degradation of Optically Active Depsipeptide Copolymers, J. Biomater. Sci., Polym. Ed., 10, 621 (1999).

[33] H. Shirahama, K. Mizuma, K. Umemoto, and H. Yasuda, Synthesis of Poly(lactide-ran-MOHEL) and Its Biodegradation with Proteinase K, J. Polym. Sci.Polym. Chem. Ed., 39, 1374 (2001).

[34] H. Shirahama, A. Kantani, and H. Yasuda, Synthesis and Biodegradability of Copolymers of Ethylene Carbonate with Lactones, Polymer J., 32, 280.

著書：

[1]安田源ら、高分子化学、朝倉書店(1994), [2]安田源ら、機能性材料科学、朝倉書店(1999), [3]安田源、均一系遷移金属触媒によるリビング重合、IPC (1999), [4]安田源、最先端高分子、三田出版(1995).

CITATION INDEX:　　　　　　　　　　　　　　　　　　　(2004.1.14)

Journal Count

1) J. Am. Chem. Soc., 114, 4908 (1992)
231

2) Acc. Chem. Res., 18, 120 (1985)
202

3) Angew. Chem., Int. Ed. Engl., 26, 723 (1987)
199

4) Macromolecules, 26, 7134 (1993)
165

5) Organometallics, 1, 388 (1982)
140

6) Macromolecules, 25, 5115 (1992)
129

7) J. Am. Chem. Soc., 107, 2410 (1985)
119

8) Bull. Chem. Soc. Jpn., 52, 2036 (1979)
91

9) Organometallics, 3, 1470 (1984)
78

10) J. Organomet. Chem., 285, 15 (1985)
77

11) Macromol. Chem. Phys., 196, 2417 (1995)
74

12) Prog. Polym. Sci., 18, 1097 (1993)
70

13) Chem. Lett., 519 (1981)
66

14) Chem. Lett., 671 (1981)
56

15) J. Chem. Soc., Chem. Commun., 1094 (1990)
54

16) Bull. Chem. Soc. Jpn., 70, 1745 (1981)
53

17) Bull. Chem. Soc. Jpn., 53, 1098 (1980)
50

Total number of publications:

Regular articles 261

Reviews and books 99

受賞歴：

高分子学会賞(1994), 日本希土類学会賞(1995)

所属学会：

日本化学会、高分子学会、炭素材料学会、日本希土類学会、触媒学会、有機合成協会、近畿化学会、米国化学会、＜役員歴＞第４５回高分子討論会実行委員長(1996), 高分子学会中四国支部理事(1993-2004、支部長(2000-2002))

社会での活動：

文部省学術審査会専門委員(1997-1999),　日本学術振興会特別研究員等審査会委員(1998-1999), 日本化学会常議員(1998-1999), 精密触媒重合研究開発総合調査委員(1997-1999)

高分子化学のホームページに戻る

Journal	Count

1) J. Am. Chem. Soc., 114, 4908 (1992)	231
2) Acc. Chem. Res., 18, 120 (1985)	202
3) Angew. Chem., Int. Ed. Engl., 26, 723 (1987)	199
4) Macromolecules, 26, 7134 (1993)	165
5) Organometallics, 1, 388 (1982)	140
6) Macromolecules, 25, 5115 (1992)	129
7) J. Am. Chem. Soc., 107, 2410 (1985)	119
8) Bull. Chem. Soc. Jpn., 52, 2036 (1979)	91
9) Organometallics, 3, 1470 (1984)	78
10) J. Organomet. Chem., 285, 15 (1985)	77
11) Macromol. Chem. Phys., 196, 2417 (1995)	74
12) Prog. Polym. Sci., 18, 1097 (1993)	70
13) Chem. Lett., 519 (1981)	66
14) Chem. Lett., 671 (1981)	56
15) J. Chem. Soc., Chem. Commun., 1094 (1990)	54
16) Bull. Chem. Soc. Jpn., 70, 1745 (1981)	53
17) Bull. Chem. Soc. Jpn., 53, 1098 (1980)	50